MnS夹杂物诱发钢材点蚀综述

doi:10.13228/j.boyuan.issn1006-9356.20220425

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摘要 MnS夹杂物诱发钢材点蚀,对钢材服役寿命、工作生产安全和社会经济发展产生巨大危害。首先,分析了MnS夹杂物诱发钢材点蚀的机理,包括电偶腐蚀机理、S和Cl^-协同作用机理、封闭区域加速点蚀机理、贫铬区机理和微缝隙机理;其次,汇总了MnS夹杂物大小、形貌、分布,Cl^-浓度、温度和应力对MnS夹杂物诱发钢材点蚀的影响;然后,总结了钢材防腐蚀的常用措施;最后,展望了防止MnS夹杂物诱发钢材点蚀的未来研究方向。

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	胡锦榛
	任英
	张继
	张立峰

关键词 ： MnS, 点蚀, 电偶腐蚀, 贫铬区, 微缝隙

Abstract：The pitting corrosion of steel induced by MnS inclusions is extremely harmful to the service life of steel, safe production and socioeconomic development. Firstly, mechanisms of pitting corrosion for steel induced by MnS inclusions are analyzed, including the mechanism of galvanic corrosion, the synergistic mechanism of S and Cl^-, the mechanism of accelerating pitting corrosion in closed area, the mechanism of Cr-depleted zone and the mechanism of micro-crevice. Secondly, the effects of MnS inclusions size, morphology, distribution, and chloride ion concentration, temperature and stress on pitting corrosion induced by MnS inclusions are summarized. Then, prevention measurements of the steel corrosion are summarized. Finally, the future research direction of preventing the pitting corrosion of steel induced by MnS inclusions is proposed.

Key words： MnS inclusion pitting corrosion galvanic corrosion Cr-depleted zone micro-crevice

收稿日期: 2022-05-05

基金资助:国家自然科学基金资助项目(51874031, U1860206, 52174293); 河北省省级科技计划资助项目(20311004D)

通讯作者: 张立峰(1972—), 男, 博士, 教授; E-mail: zhanglifeng@ncut.edu.cn

作者简介: 胡锦榛(1997—), 男, 硕士生; E-mail: hujz459@163.com

引用本文:

胡锦榛, 任英, 张继, 张立峰. MnS夹杂物诱发钢材点蚀综述[J]. 中国冶金, 2022, 32(11): 18-31. HU Jin-zhen, REN Ying, ZHANG Ji, ZHANG Li-feng. Review on pitting corrosion of steel induced by MnS inclusions[J]. China Metallurgy, 2022, 32(11): 18-31.

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http://www.zgyj.ac.cn/CN/10.13228/j.boyuan.issn1006-9356.20220425 或 http://www.zgyj.ac.cn/CN/Y2022/V32/I11/18

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