Research progress of liquid metal atomization technology and preparation of its amorphous powders
LIU Jia-qi1, PANG Jing2, WANG Pu1, YANG Dong2, LI Xiao-yu2, ZHANG Jia-quan1
1. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China; 2. Qingdao Yunlu Advanced Materials Technology Co., Ltd., Qingdao 266232, Shandong, China
Abstract:In the face of challenge for green and low-carbon development and energy structure upgrading, communication and electronic electric industries are increasingly demanding large current power inductors. As the raw material of magnetic powder core of advanced inductors urgently needed, amorphous powders have excellent magnetic conductivity at high frequency, thermal stability and corrosion resistance, which are far superior to other soft magnetic materials presently. However, as a kind of metastable material with short-range order and long-range disorder in atomic structure, production of amorphous powders is still one of the big challenges. Recently, liquid alloy atomization has become one of the main methods for the production of amorphous alloy powders with the advantages of stable powder properties, high cooling rate and mass production. Based on the analysis of characteristics and formation mechanism of amorphous materials, the principle and development of amorphous alloy powder prepared by gas atomization and water atomization are systematically described, and the current understanding of melt break-up and solidification mechanism in atomization process is summarized. Finally, several unsolved problems and the research status in the field of atomization are pointed out to provide some inspiration for atomization technology of amorphous powders.
刘佳奇, 庞靖, 王璞, 杨东, 李晓雨, 张家泉. 液态金属雾化成形及非晶合金制粉的研究进展[J]. 中国冶金, 2022, 32(2): 1-14.
LIU Jia-qi, PANG Jing, WANG Pu, YANG Dong, LI Xiao-yu, ZHANG Jia-quan. Research progress of liquid metal atomization technology and preparation of its amorphous powders[J]. China Metallurgy, 2022, 32(2): 1-14.
Gay D E. Soft magnetic composite materials for ac electrical applications[J]. Metal Powder Report,1997,52(7/8):42.
[5]
Petzold J. Advantages of softmagnetic nanocrystalline materials for modern electronic applications[J]. Journal of Magnetism and Magnetic Materials,2002,242(P1):84.
Duwez P. Effect of rate of cooling on the alpha-beta transformation in Titanium and Titanium-Molybdenum alloys[J]. Transaction Metallic Society AIME,1951,3(9):765.
CHEN H,HE Y,Shiflet G J,et al. Mechanical properties of partially crystallized aluminum based metallic glasses[J]. Scripta Metallurgica Et Materialia,1991,25(6):1421.
[31]
MA Y,WANG Q,ZHOU X,et al. A novel soft-magnetic B2-based multiprincipal-element alloy with a uniform distribution of coherent body-centered-cubic nanoprecipitates[J]. Advanced Materials,2021,33(14):e2006723.
[32]
Michael E McHenry,Matthew A Willard,David E Laughlin. Amorphous and nanocrystalline materials for applications as soft magnets[J]. Progress in Materials Science,1999,44(4):294.
WANG W H,DONG C,Shek C H. Bulk metallic glasses[J]. Materials Science & Engineering R,Reports,2004,44(2/3):45.
[36]
SHEN Jun,CHEN Qing-jun,SUN Jian-fei,et al. Exceptionally high glass-forming ability of an FeCoCrMoCBY alloy [J]. Applied Physics Letters,2005,86(15):279.
[37]
LI H X, GAO J E, JIAO Z B,et al. Glass-forming ability enhanced by proper additions of oxygen in a Fe-based bulk metallic glass[J]. Applied Physics Letters,2009,95(16):161905.1.
[38]
LUO C Y,ZHAO Y H,XI X K,et al. Making amorphous steel in air by rare earth microalloying[J]. Journal of Non-Crystalline Solids,2006,352(2):185.
[39]
Waniuk T A,Busch R,Masuhr A,et al. Equilibrium viscosity of the Zr41.2Ti13.8Cu12.5Ni10Be22.5 bulk metallic glass-forming liquid and viscous flow during relaxation phase separation and primary crystallization[J]. Acta Materialia,1998,46(15):5229.
[40]
LU Y,HUANG Y,ZHENG W,et al. Free volume and viscosity of Fe-Co-Cr-Mo-C-B-Y bulk metallic glasses and their correlation with glass-forming ability[J]. Journal of Non-Crystalline Solids,2012,358(10):1274.
Jason Ting,Iver E Anderson. A computational fluid dynamics (CFD) investigation of the wake closure phenomenon[J]. Materials Science and Engineering A,2004,379(1):264.
[49]
松山芳治,三谷裕康,铃木寿.粉末冶金学[M].周安生,高一平,译.北京:科学出版社,1978.
[50]
Grant N J. A review of various atomization processes[C]// Rapid solidification processing:Principles and Technologies Ⅱ. Batcon Rouge,LA:Clator’s Pub. Div. 1980:273.
[51]
Rutharde R. Novel aspects for high quality metal powders equipment[J]. Powder Metallurgy International,1981,13(4):175.
[52]
Walz A,Kurzann A. Metal powders and a process for the production:US Patent,4534917[P]. 1985-12-29.
[53]
Anderson I E. Boost in atomizer pressure shaves powder particle size[J]. Advanced Materials and Processes,1991(7):30.
[54]
Miller S A. Close-coupled gas atomisation of metal alloy [C]// Horizons of powder metallurgy. Freiberg,Germany:Verlag Schmidt GMBH,1986,42:29.
[55]
陈欣. 紧耦合气雾化流场结构和雾化机理研究[D].长沙:中南大学,2007.
[56]
Hopkins W G. Close-coupled gas atomization comes of age[J]. Metal Powder Report,1994,49(3):34.
[57]
Schulz G. NANOVAL process offers fine powder benefits[J]. Metal Powder Report,1996,51(11):30.
[58]
Strauss J T. Hotter gas increases atomization efficiency[J]. Metal Powder Report,1999,54(11):24.
[59]
Schulz G. Taking the pressure out of atomization[J]. Metal Powder Report,2002,57(11):23.
[60]
Achelis L,Uhlenwinkel V. Characterisation of metal powders generated by a pressure-gas-atomiser[J]. Materials Science & Engineering A,2008,477(1/2):15.
[61]
Czisch C,Fritsching U. Atomizer design for viscous-melt atomization[J]. Materials Science and Engineering A,2008,477(1/2):21.
[62]
Rieken J,Heidloff A,Anderson I E. Moving towards improved ultra-fine powder production for precursor ODS Fe-based alloys[J]. Advances in Powder Metallurgy and Particulate Materials,2013,2:11.
Ohnaka I,Yamauchi I,Kawamoto S,et al. Production and properties of rapidly solidified Al-4.5%Cu alloy powder by the rotating-water-atomization process [J]. Journal of Materials Science,1985,20(6):2148.
[69]
Ohnaka I,Fukusako T,Tsutsumi H. Production of Fe40Ni40B20 powder by rotating-water-atomization process[J]. Transactions of the Japan Institute of Metals,2007,26(1):52.
Endo I,Otsuka I,Okuno R,et al. Fe-based amorphous soft-magnetic powder produced by spinning water atomization process (SWAP)[J]. IEEE Trans Magn,1999,35(5):3385.
[74]
Otsuka I,Wada K,Maeta Y,et al. Magnetic properties of Fe-based amorphous powders with high-saturation induction produced by spinning water atomization process (SWAP)[J]. IEEE Transactions on Magnetics,2008,44(11):3891.
[75]
See J B,Johnston G H. Interactions between nitrogen jets and liquid lead and tin streams[J]. Powder Technology,1978,21(1):119.
[76]
Debayan Dasgupta,Nath Sujit,Mukhopadhyay Achintya,et al. Linear and non-linear analysis of breakup of liquid sheets:a review[J]. Journal of the Indian Institute of Science,2019,99(1):59.
[77]
Hinze J O. Fundamentals of hydrodynamics of splitting in dispersion processes[J]. AIChE Journal,1955,1(3):289.
[78]
郭秋松. 溶液雾化法制备镍钴精细粉体材料理论与工艺研究[D].长沙:中南大学,2010.
[79]
HE Wen-chao,LV Xue-wei,PAN Fei-fei,et al. Preparation of iron powders using rotary cup atomizer with water curtain[J]. Powder Technology,2020,364(15):300.
Seki Y,Okamoto S,Takigawa H,et al. Effect of atomization variables on powder characteristics in the high-pressured water atomization process[J]. Metal Powder Report,1990,45(1):38.
[82]
Neikov O D. Atomization and granulation-science direct[M]//Neikow O D, Naboychenko S S, Murashova I V, et al. Handbook of Non-Ferrous Metal Powders: Technologies and Applications. Oxford: Elsevier, 2019.
[83]
DU Kai-ping,GAO Xiang-zhou,LI Zheng-qiu. Numerical analysis on secondary breakup process of metal droplet in gas atomization[J]. Atomization and Sprays,2019,29(5):455.
[84]
Lord Rayleigh. On the instability of jets[J]. Proceedings of the London Mathematical Society,1878,s1-10(1):4.
[85]
WANG P,LI J,LIU H S,et al. Process modeling gas atomization of close-coupled ring-hole nozzle for 316L stainless steel powder production[J]. Chinese physics B,2021,30(5):617.
[86]
WANG P,LI J,WANG X,et al. Close-coupled nozzle atomization integral simulation and powder preparation using vacuum induction gas atomization technology[J]. Chinese physics B,2021,30(2):487.
[87]
Clark C J,Dombrowski N. Aerodynamic instability and disintegration of inviscid liquid sheets[J]. Proceedings of the Royal Society A:Mathematical and Physical Sciences,1972,329:467.
[88]
Bradley D. On the atomization of liquids by high-velocity gases[J]. Journal of Physics D Applied Physics,1973,6(14):1724.
[89]
Taisuke Nambu,Mizobuchi Yasuhiro. Detailed numerical simulation of primary atomization by crossflow under gas turbine engine combustor conditions[J]. Proceedings of the Combustion Institute,2021,38(2):3213.
[90]
Lee T W,Greenlee B,Park J E. Computational protocol for spray flow simulations including primary atomization[J]. Journal of Fluids Engineering-Transactions of the ASME,2021,143(3):031402.
Weber C. On the breakdown of a fluid jet[J]. Z.A.M.P.,1931,11:136.
[95]
O'Rourke P J,Amsden A A. The TAB method for numerical calculation of spray drop breakup,SAE872089[R].USA:SAE,1987.
[96]
Park J C,Kim M H,Miyata H. Fully non-linear free-surface simulations by a 3D viscous numerical wave tank[J]. International Journal for Numerical Methods in Fluids,2015,29(6):685.
[97]
Reitz R D. Modeling atomization processes in high-pressure vaporizing sprays[J]. Atomization & Spray Tech,1987,3:309.
[98]
Igra D,Takayama K. Investigation of aerodynamic breakup of a cylindrical water droplet[J]. Atomization and Sprays,2001,11(2):167.
[99]
Aalburg C,Leer B V,Faeth G M. Deformation and drag properties of drops subjected to shock-wave and steady disturbances[J]. AIAA J,2003,41(12):2371.
[100]
Khosla S,Smith C. Detailed understanding of drop atomization by gas crossflow using the volume of fluid method [C]// ILASS Americas,19th annual conference on liquid atomization and spray systems. Toronto,Canada:Verlag Schmidt GMBH,2006.
Thompson J S,Hassan O,Rolland S A,et al. The identification of an accurate simulation approach to predict the effect of operational parameters on the particle size distribution (PSD) of powders produced by an industrial close-coupled gas atomizer[J]. Powder Technology,2016,291:75.
[104]
WANG P,LI J,WANG X,et al. Impact mechanism of gas temperature in metal powder production via gas atomization[J]. Chinese Physics B,2021,30(5):493.
[105]
Nichiporenko O S,Naida Y I. Heat exchange between metal particles and gas in the atomization process[J]. Soviet Powder Metallurgy and Metal Ceramics,1968,67(7):509.
[106]
库恩 H A,劳利A.粉末冶金工艺新技术及其分析[M].任崇信,译. 北京:冶金工业出版社,1982.