Effect of continuous annealing process parameters on microstructure and properties of 1 180 MPa grade Nb-microalloyed dual phase steel with high formability
YANG Yuhuan1,2, CHU Xiaohong1,2, LU Hongzhou3, HAN Yun4, YANG Feng4, ZHAO Zhengzhi1,2
1. Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing 100083, China; 2. Beijing Engineering Technology Research Center of Special Steel for Traffic and Energy, Beijing 100083, China; 3. CITIC Metal Co., Ltd., Beijing 100004, China; 4. Research Institute of Technology, Shougang Group Co., Ltd., Beijing 100043, China
Abstract:In order to achieve the goal of energy conservation and emission reduction, automobile bodies are developing towards lightweight and high-quality direction. DH steel has a wide application prospect due to its excellent strength and plasticity performance. The high formability 1 180 MPa grade Nb-microalloyed dual phase steel, exhibiting excellent properties, had been developed through laboratory simulated continuous annealing and characterization analysis of microstructure and properties. The results of continuous annealing tests reveal that the increase of annealing temperature lead to corresponding rise in the content of martensite and bainite, consequently resulting in enhancement of tensile strength up to 1 200 MPa at 870 ℃. As the annealing temperature further increases, the volume fraction of tempered martensite and the bainite increases, resulting in slight decrease in strength. As the over-aging temperature increases, the tensile strength gradually decreases and the elongation increases to 16.2% at 370 ℃. Based on the continuous annealing test results and the feature of industrial production line, DH1180 continuous annealing plates was industrially produced. Its microstructure is composed of ferrite, martensite, bainite, and residual austenite(φ(γ)=6.62%), dispersed with nano-scaled (Nb,Ti)C precipitates, showing superior match of strength and plasticity with tensile strength of 1 257 MPa and elongation of 15.6%. The development and application of DH1180 steel provides more possibilities for high-strength steel for automobile.
杨玉环, 褚晓红, 路洪洲, 韩赟, 阳锋, 赵征志. 连续退火工艺参数对1 180 MPa级含Nb增强成形性双相钢组织性能的影响[J]. 中国冶金, 2024, 34(1): 72-80.
YANG Yuhuan, CHU Xiaohong, LU Hongzhou, HAN Yun, YANG Feng, ZHAO Zhengzhi. Effect of continuous annealing process parameters on microstructure and properties of 1 180 MPa grade Nb-microalloyed dual phase steel with high formability[J]. China Metallurgy, 2024, 34(1): 72-80.
康永林, 朱国明. 中国汽车发展趋势及汽车用钢面临的机遇与挑战[J]. 钢铁, 2014, 49(12): 1.(KANG Y L, ZHU G M. Development trend of China's automobile industry and the opportunities and challenges of steels for automobiles[J]. Iron and Steel, 2014, 49(12): 1.)
[2]
姚同路, 吴伟, 杨勇, 等. “双碳”目标下中国钢铁工业的低碳发展分析[J]. 钢铁研究学报, 2022, 34(6): 505.(YAO T L, WU W, YANG Y, et al. Analysis on low-carbon development of China's steel industry under dual-carbon goal[J]. Journal of Iron and Steel Research, 2022, 34(6): 505.)
[3]
张琦, 田硕硕, 沈佳林. 中国钢铁行业碳达峰碳中和时间表与路线图[J]. 钢铁, 2023, 58(9): 59.(ZHANG Q, TIAN S S, SHEN J L. Roadmap and timetable for achieving carbon peak and carbon neutrality of China's iron and steel industry[J]. Iron and Steel, 2023, 58(9): 59.)
[4]
彭孝仁. 我国汽车行业用钢市场分析[J]. 冶金经济与管理, 2021(6): 26.(PENG X R. Analysis of steel market in China automobile industry[J]. Metallurgical Economics and Management, 2021(6): 26.)
[5]
FRANK C. Current trends in automotive lightweighting strategies and materials[J]. Materials, 2021, 14(21): 6631.
[6]
王存宇, 杨洁, 常颖, 等. 先进高强度汽车钢的发展趋势与挑战[J]. 钢铁, 2019, 54(2): 1.(WANG C Y, YANG J, CHANG Y, et al. Development trend and challenge of advanced high strength automobile steels[J]. Iron and Steel, 2019, 54(2): 1.)
[7]
周峰峦, 王存宇, 曹文全, 等. 热轧逆相变退火中锰钢的疲劳性能[J]. 钢铁, 2020, 55(12): 87.(ZHOU F L, WANG C Y, CAO W Q, et al. Fatigue properties of hot-rolled medium manganese steel treated by ART-annealing[J]. Iron and Steel, 2020, 55(12): 87.)
[8]
邹英, 刘华赛, 韩赟, 等. 汽车用热基镀锌高强钢的研发进展[J]. 钢铁, 2022, 57(12): 118.(ZOU Y, LIU H S, HAN Y, et al. Research and development progress of hot-rolled galvanized high-strength steel for automobile[J]. Iron and Steel, 2022, 57(12): 118.)
[9]
王卫卫, 李光灜, 张江玲, 等. 含铌冷轧DP780钢的连退工艺对组织及性能的影响[J]. 钢铁, 2016, 51(6): 71.(WANG W W, LI G Y, ZHANG J L, et al. Effect of continuous annealing process on microstructure and properties of DP780 containing niobium[J]. Iron and Steel, 2016, 51(6): 71.)
[10]
索忠源, 杜阳, 付立铭, 等. 退火温度对铁素体/马氏体双相钢组织及性能的影响[J]. 金属热处理, 2020, 45(9): 125.(SUO Z Y, DU Y, FU L M, et al. Effect of annealing temperature on microstructure and properties of ferrite/martensite dual-phase steel[J]. Heat Treatment of Metals, 2020, 45(9): 125.)
[11]
余灿生, 郑之旺, 常智渊, 等. 热镀锌工艺对1 180 MPa级双相钢组织性能的影响[J]. 中国冶金, 2023, 33(6): 108.(YU C S, ZHENG Z W, CHANG Z Y, et al. Effect of hot-dip galvanizing process on microstructure and properties of 1 180 MPa grade dual-phase steel[J]. China Metallurgy, 2023, 33(6): 108.)
[12]
肖洋洋, 詹华, 崔磊, 等. 1 000 MPa级微合金化冷轧双相钢退火工艺及强韧化机制[J]. 钢铁研究学报, 2019, 31(10): 912.(XIAO Y Y, ZHAN H, CUI L, et al. An investigation on annealing process and strengthening and toughening mechanism of 1 000 MPa grade microalloyed cold-rolled dual-phase steel[J]. Journal of Iron and Steel Research, 2019, 31(10): 912.)
[13]
储双杰, 毛博, 胡广魁. 汽车用先进高强度冷轧双相钢的显微组织调控和强韧化机理[J]. 金属学报, 2022, 58(4): 551.(CHU S J, MAO B, HU G K. Microstructure control and strengthening mechanism of high strength cold rolled dual phase steels for automobile applications[J]. Acta Metallurgica Sinica, 2022, 58(4): 551.)
[14]
赵征志, 陈伟健, 高鹏飞, 等. 先进高强度汽车用钢研究进展及展望[J]. 钢铁研究学报, 2020, 32(12): 1059.(ZHAO Z Z, CHEN W J, GAO P F, et al. Progress and perspective of advanced high strength automotive steel[J]. Journal of Iron and Steel Research, 2020, 32(12): 1059.)
[15]
刘雪丽, 黄赓. 双相钢冲压翻边开裂的影响因素分析[J]. 工程技术研究, 2021, 6(12): 13.(LIU X L, HUANG G. Analysis of factors for the flange cracking of dual phase steel[J]. Engineering and Technology Research, 2021, 6(12): 13.)
[16]
祝洪川, 孙宜强, 吴青松. 先进高强钢断裂性能研究[J]. 锻压技术, 2015, 40(12): 115.(ZHU H C, SUN Y Q, WU Q S. Study on the fracture performance of AHSS[J]. Forging and Stamping Technology, 2015, 40(12): 115.)
[17]
汪淼, 张聪, 胡锋,等. 相变诱导塑性汽车用钢的发展现状与趋势[J]. 钢铁研究学报, 2016, 28(8): 1.(WANG M, ZHANG C, HU F,et al. Current status and trend of TRIP automotive steels[J]. Journal of Iron and Steel Research, 2016, 28(8): 1.)
[18]
杜一飞, 黎旺, 田亚强. Nb、V、Ti微合金化在汽车用TRIP钢中的应用进展[J]. 金属热处理, 2019, 44(8): 50.(DU Y F, LI W, TIAN Y Q. Application progress of Nb, V and Ti microalloying in TRIP steel for automobile[J]. Heat Treatment of Metals, 2019, 44(8): 50.)
[19]
李伟, 贾兴祺, 金学军. 高强韧QPT工艺的先进钢组织调控和强韧化研究进展[J]. 金属学报, 2022, 58(4): 444.(LI W, JIA X Q, JIN X J. Research progress of microstructure control and strengthening mechanism of QPT process advanced steel with high strength and toughness[J]. Acta Metallurgica Sinica, 2022, 58(4): 444.)
[20]
路洪洲, 马鸣图, 郭爱民. 汽车EVI技术进展[J]. 汽车工艺与材料, 2022(8): 1.(LU H Z, MA M T, GUO A M. Development of automotive EVI technologies[J]. Automotive Technology and Materials, 2022(8): 1.)
[21]
朱国森, 韩赟, 蒋光锐, 等. 汽车车身用新型冷轧薄板研发进展[J]. 工程科学学报, 2022, 44(9): 1585.(ZHU G S, HAN Y, JIANG G R, et al. Research and development progress of new cold rolled sheet steels of car body[J]. Chinese Journal of Engineering, 2022, 44(9): 1585.)
[22]
中国国家标准化管理委员会.汽车用高强度冷连轧钢板及钢带: 第2部分 双相钢: GB/T 20564.2—2017[S]. 北京:中国标准出版社,2017.(Standardization Administration of China. Continuously cold rolled high strength steel sheet and strip for automobile: Part 2 Dual phase steel: GB/T 20564.2—2017[S]. Beijing: China Standards Press,2017.)
[23]
中国国家标准化管理委员会. 汽车用高强度冷连轧钢板及钢带:第12部分 增强成形性双相钢:GB/T 20564.12—2019[S]. 北京:中国标准出版社,2019.(Standardization Administration of China. Continuously cold rolled high strength steel sheet and strip for automobile:Part 12: Dual phase steel with high formability: GB/T 20564.12-2019[S]. Beijing: China Standards Press, 2019.)
[24]
刘浩, 杨世印, 高鹏. 780DH后减振器支座开裂问题解决[J]. 汽车制造业, 2022(1): 36.(LIU H, YANG S Y, GAO P. Solution to cracking problem of 780DH rear shock absorber support[J]. Automobile Industry, 2022(1): 36.)
[25]
孙航. 超高强增强成形性双相钢组织性能研究[D]. 北京: 北京科技大学, 2021.(SUN H. Research on Microstructure and Properties of Ultra-high Strength Dual Phase Steel with High Formability[D]. Beijing: University of Science and Technology Beijing, 2021.)
[26]
周莉, 薛仁杰, 曹晓恩, 等. 高铝增强成形性双相钢980DH组织性能研究[J]. 钢铁钒钛, 2022, 43(2): 186.(ZHOU L, XUE R J, CAO X E, et al. Study on microstructure and properties of high aluminum dual phase steel 980DH with high formability[J]. Iron Steel Vanadium Titanium, 2022, 43(2): 186.)
[27]
梁江涛, 赵征志, 刘锟, 等. 1 300 MPa级Nb微合金化DH钢的组织性能[J]. 工程科学学报, 2021, 43(3): 392.(LIANG J T, ZHAO Z Z, LIU K, et al. Microstructure and properties of 1 300 MPa grade Nb microalloying DH steel[J]. Chinese Journal of Engineering, 2021, 43(3): 392.)
[28]
王保磊, 王俊峰, 王华, 等. 退火工艺对新型DH钢显微组织和力学性能的影响[J]. 上海金属, 2022, 44(6): 48.(WANG B L, WANG J F, WANG H, et al. Effect of annealing process on microstructure and mechanical properties of a new type of DH steel[J]. Shanghai Metals, 2022, 44(6): 48.)
[29]
于晓飞, 曹晓恩, 薛仁杰, 等. 1.0 GPa级冷轧增强成形性双相钢的组织性能[J]. 材料热处理学报, 2022, 43(12): 116.(YU X F, CAO X E, XUE R J, et al. Microstructure and properties of 1.0 GPa grade cold rolled dual phase steel with high formability[J]. Transactions of Materials and Heat Treatment, 2022, 43(12): 116.)
[30]
中国国家标准化管理委员会. 金属材料 拉伸试验: 第1部分 室温试验方法: GB/T 228.1—2021[S]. 北京:中国标准出版社,2021.(Standardization Administration of China. Metallic materials Tensile testing:Part 1 Method of test at room temperature: GB/T 228.1—2021[S]. Beijing: China Standards Press, 2021.)
[31]
范雄. 金属X射线学[M]. 北京: 机械工业出版社, 1989.(FAN X. Metal X-Ray Analysis[M]. Beijing: China Machine Press, 1989.)
[32]
孙航, 褚晓红, 唐梦霞, 等. 1 500 MPa级高伸长率双相钢的组织性能分析[J]. 中国冶金, 2022, 32(4): 47.(SUN H, CHU X H, TANG M X, et al. Microstructure and properties analysis of 1 500 MPa grade high elongation dual phase steel[J]. China Metallurgy, 2022, 32(4): 47.)
[33]
徐祖耀, 陈卫中. 奥氏体强化和其中碳含量对马氏体及贝氏体相变的影响[J]. 上海金属, 1990, 12(4): 3.(XU Z Y, CHEN W Z. Effect of strength and carbon content of austenite on martensitic and bainitic transformations[J]. Shanghai Metals, 1990,12(4): 3.)
[34]
田亚强, 王安东, 郑小平, 等. 高温形变对Q&P处理低碳钢中残留奥氏体稳定性的影响[J]. 金属热处理, 2018, 43(6): 106.(TIAN Y Q, WANG A D, ZHENG X P, et al. Effect of high temperature deformation on stability of retained austenite for Q&P treated low carbon steel[J]. Heat Treatment of Metals, 2018, 43(6): 106.)
[35]
XIONG X C, CHEN B, HUANG M X, et al. The effect of morphology on the stability of retained austenite in a quenched and partitioned steel[J]. Scripta Materialia, 2013, 68(5): 321.
[36]
CAI M, CHEN L, FANG K, et al. The effects of a ferritic ormartensitic matrix on the tensile behavior of a nano-precipitation strengthened ultra-low carbon Ti-Mo-Nb steel[J]. Materials Science and Engineering A, 2021, 801: 1404.
[37]
宋少威, 董明振, 尉文超, 等. 17Cr2Ni2MoVNb齿轮钢中NbC析出相对晶粒长大的影响[J]. 金属热处理, 2023, 48(1): 122.(SONG S W, DONG M Z, WEI W C, et al. Effect of NbC precipitates on grain growth of 17Cr2Ni2MoVNb gear steel[J]. Heat Treatment of Metals, 2023, 48(1):122.)