Research status and prospects of copper slag resource recovery
XUE Chao-long1,2, LI Hui1,2, LIANG Jing-long1,2, XU Yan-ke1,2
1. College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063009, Hebei, China;
2. Key Laboratory of Ministry of Education for Modern Metallurgy Technology, Tangshan 063009, Hebei, China
The current domestic and foreign research status on the recovery of valuable elements in copper slag and the comprehensive utilization of resources are reviewed. For high-grade iron in copper slag, the advantages and disadvantages of iron resource recovery treatment were discussed and studied mainly from the oxidation roasting magnetic separation method and the direct roasting reduction method. For non-ferrous metals such as cobalt, zinc, copper, gold, silver, and aluminum, the element recovery rate and recovery process were compared. According to the phase composition of the copper slag itself, the application status of the copper slag in the preparation of building materials, glass-ceramics and wastewater treatment was explained. The future application and research direction of copper slag were prospected.
MENG X Y,LI Y,WANG H Y,et al. Effects of Na2O additions to copper slag on iron recovery and the generation of ceramics from the non-magnetic residue[J]. Journal of Hazardous Materials,2020,399:122845.
Sudarvizhi M S. Ilangovan R. Performance of copper slag and ferrous slag as partial replacement of sand in concrete[J]. International Journal of Civil and Structural Engineering,2013,1(4):918.
[5]
汤海波. 铜冶炼主要副产物处理与综合利用工艺研究[D]. 武汉:武汉科技大学,2014.
[6]
彭容秋. 铜冶金[M]. 长沙:中南大学出版社,2004:11.
[7]
Hassan Z,Ali M,Reza I,et al. Effect of copper slag on performance of warm mix asphalt[J]. International Journal of Pavement Engineering,2019,20(7):775.
Semykina A,Shatokha V,Iwase M,et al. Kinetics of oxidation of divalent iron to trivalent state in liquid FeO-CaO-SiO2 slags[J]. Metallurgical and Materials Transactions B,2010,41(6):1230.
[10]
LIN Z,HUI U C,RONG D D,et a1. Growth behavior of iron grains during deep reduction of copper slag[J]. Powder Technology,2020,367:157.
LI Q,YANG F,WANG Z,et al. Study on mechanism of oxidation modification of copper slag[J]. Transactions of the Indian Institute of Metals,2019,72(12):3223.
[15]
JIANG P G,LIU J S,XIAO Y Y,et al. Recovery of iron from copper slag via modified roasting in CO-CO2 mixed gas and magnetic separation[J]. Journal of Iron and Steel Research International,2020,27(6):1.
ZHOU X L,ZHU D Q,PAN J,et al,Utilization of waste copper slag to produce directly reduced iron for weathering resistant steel[J]. ISIJ International,2015,55(7):1347.
Nadirov R,Syzdykova L,Zhussupova A. Copper smelter slag treatment by ammonia solution:leaching process optimization[J]. Journal of Central South University,2017,24(12):2799.
[23]
Ahmed I M,Nayl A A,Daound J A. Leaching and recovery of zinc and copper from brass slag by sulfuric acid[J]. Journal of Saudi Chemical Society,2016,20:280.
Murayyov M I,Fomchenko N V. Leaching of nonferrous metals from copper converter slag with application of acidophilic microorganisms[J]. Applied Biochemistry and Microbiology,2013,49(6):562.
Filcenco O A,Dobre T,Panturu E,et al. Experimental process analysis and mathematical modeling for selective gold leaching from slag through wet chlorination[J]. Hydrometallurgy,2014,144/145:170.
Sharifi Y,Afshoon I,Asad-Abadi S,et al. Environmental protection by using waste copper slag as a coarse aggregate in self-compacting concrete[J]. Journal of Environmental Management,2020,271:111013.
[37]
WANG D,WANG Q,HUANG Z. Reuse of copper slag as a supplementary cementitious material:Reactivity and safety[J]. Resources,Conservation and Recycling,2020,162:105037.
Najimi M,Sobhani J,Pourkhorshidi A. Electrochemical impedance behavior of concrete containing natural zeolite and copper slag[J]. Asian Journal of Civil Engineering,2019,20(6):847.
[40]
YONG K L,XING Z,XIAN J Q,et.al. Efficient removal of arsenic from copper smelting wastewater in form of scorodite using copper slag[J]. Journal of Cleaner Production,2020,270:122428.
DAI W B,LI Y,CANG D Q,et al. Research on a novel modifying furnace for converting hot slag directly into glass-ceramics[J]. Journal of Cleaner Production,2018,172:169.