CAO Linxiang, LUO Guoping, WANG Ziwei, SUN Quan, BAI Xiaoguang, LIU Shuguang, LIU Jingquan
In order to reveal the formation rules of fluorine, potassium and sodium gases in the process of blast furnace smelting, the No.7 blast furnace at Baotou Steel Group was taken as an example, and the blast furnace was segmented into four distinct thermal regions along its vertical axis. According to the main chemical reactions in different regions, the mixed charge composition and gas composition at any temperature along the height of blast furnace were obtained by using the difference calculation method through the amount of raw material and fuel, the composition of raw material and fuel and the composition of hearth gas. The gas pressure loss in different temperature regions and the gas pressure at any temperature of blast furnace were determined by combining the Ergun equation, the mixed ore droplet experiment with the hot blast pressure of blast furnace and the top gas pressure of blast furnace. Based on the composition of mixed burden, gas composition, gas pressure and reaction temperature at any temperature of blast furnace, FactSage7.1 thermodynamic software was used to simulate the formation reactions of fluorine (F), potassium (K) and sodium (Na) gases in different temperature regions of blast furnace. The simulation results show that in the range of 200-800℃, the production of F, K and Na gases is less, mainly HF and a small amount of KF. In the range of 800-1 025℃, the amount of gas containing F, K and Na increases. In the soft melt zone of 1 025-1 365℃, the maximum production of KCN, NaCN and KF increases significantly, reaching 1.74, 1.06 and 1.08 kg/t, respectively. In the drip zone of 1 365-1 500℃, the amount of alkali metal gases NaCN, KCN, K and Na is the largest. This study can lay a foundation for further understanding the influence of cyclic enrichment of fluorine, potassium and sodium gases on the properties of ore, coke and lining.