Review of Te treatment to control MnS inclusions in steel
ZHOU Quanlei1, YANG Wen1, ZHANG Lifeng2
1. School of Metallurgy and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China; 2. School of Mechanical and Materials Engineering, North China University of Technology, Beijing 100144, China
Abstract:With the development of steel industry towards high speed and precision, sulfur is usually added to steel to improve its workability. The morphology and distribution of manganese sulfide inclusions in steel have an important influence on steel properties. The goal of manganese sulfide inclusions control is to avoid the generation of large size manganese sulfide and to obtain spindle-shaped manganese sulfide as small and uniform distribution as possible. By adding appropriate sulfur elements and controlling the size and morphology of manganese sulfide inclusions, the free-cutting steel can obtain excellent workability while maintaining strength and toughness. The addition of tellurium can adjust the size and morphology of sulfide in steel, and the MnS inclusions are modified to MnTe-MnS inclusions during solidification, which are usually spherical or nearly spherical, reduces the proportion of large-sized dendritic manganese sulfide and improves the mechanical properties and cutting performance of steel. When the tellurium-sulfur mass ratio in steel is higher than 0.2, the aspect ratio of sulfide in steel will be significantly reduced, and the workability and cutting properties of steel will be improved. The mechanism of Te treatment on the modification of manganese sulfide inclusions in steel and the law and mechanism of tellurium influence on cutting properties of steel are summarized and elaborated, so as to provide reference for further research and development of Te application in steel industry.
周全磊, 杨文, 张立峰. 碲处理控制钢中硫化锰夹杂物综述[J]. 中国冶金, 2023, 33(10): 8-16.
ZHOU Quanlei, YANG Wen, ZHANG Lifeng. Review of Te treatment to control MnS inclusions in steel[J]. China Metallurgy, 2023, 33(10): 8-16.
AKASAWA T,SAKURAI H,NAKAMURA M,et al. Effects of free-cutting additives on the machinability of austenitic stainless steels[J]. Journal of Materials Processing Technology,2003,143:66.
[2]
QIN C J,XIA M Z,MA M Y,et al. Effects of tuning the microstructure on the mechanical properties and machinability of free-cutting steels[J]. Journal of Materials Engineering and Performance,2017,26(7):3474.
[3]
LI Z A,WU D. Effect of free-cutting additives on machining characteristics of austenitic stainless steels[J]. Journal of Materials Science and Technology,2010,26(9):839.
[4]
ZHANG X W,ZHANG L F,YANG W,et al. Characterization of MnS particles in heavy rail steels using different methods[J]. Steel Research International,2017,88(1):1600080.
[5]
SIMS C E. The nonmetallic constituents of steel[J]. Transactions of the American Institute of Mining and Metallurgical Engineers,1959,215(3):367.
[6]
ITO Y,MASUMITSU N,MATSUBARA K. Formation of MnS-type inclusion in steel[J]. Tetsu-to-Hagane,1980,66(6):647.
[7]
OIKAWA K,OHTANI H,ISHIDA K,et al. The control of the morphology of MnS inclusions in steel during solidification[J]. ISIJ International,1995,35(4):402.
POPOVA I V,NASIBOV A G,GULEI G G,et al. Nonmetallic inclusions and austenite grains of steel containing tellurium[J]. Metal Science and Heat Treatment,1986,28(1):52.
[13]
ZHENG L C,MALFLIET A,WOLLANTS P,et al. Effect of surfactant te on the formation of MnS inclusions in steel[J]. Metallurgical and Materials Transactions B,2017,48(5):2447.
[14]
WANG F,GUO H,LIU W,et al. Control of MnS inclusions in high- and low-sulfur steel by tellurium treatment[J]. Materials,2019,12(7):1034.
[15]
ZHANG S,WANG F,YANG S F,et al. Sulfide transformation with tellurium treatment for Y15 free-cutting steel[J]. Metallurgical and Materials Transactions B,2019,50(5):2284.
[16]
ZHENG L C,MALFLIET A,WOLLANTS P,et al. Effect of surfactant Te on the behavior of alumina inclusions at advancing solid-liquid interfaces of liquid steel[J]. Acta Materialia,2016,120:443.
[17]
WU X Y,WU L P,XIE J B,et al. Modification of sulfide by Te in Y1Cr13 free-cutting stainless steel[J]. Metallurgical Research and Technology,2020,117(1):107.
[18]
SHEN P,YANG Q K,ZHANG D,et al. Application of tellurium in free-cutting steels[J]. Journal of Iron and Steel Research International,2018,25(8):787.
[19]
UEDA S,SUZUKI S,YOSHIKAWA T,et al. Thermodynamic property of tellurium in molten iron measured by the transpiration method[J]. ISIJ International,2017,57(3):397.
[20]
OKAMOTO H,TANNER L E. The Fe-Te (iron-tellurium) system[J]. Bulletin of Alloy Phase Diagrams,1990,11(4):371.
[21]
GUPTA G,ROBERTSON D G C,SCHLESINGER M E. Tellurium thermodynamics in austenitic iron[J]. Canadian Metallurgical Quarterly,2005,44(3):351.
[22]
MANN G S,VAN VLACK L H. Fe1.2Te-MnTe phase relationships in the presence of excess iron[J]. Metallurgical Transactions B,1977,8(1):53.
[23]
SCHLESINGER M E. The Mn-Te (manganese-tellurium) system[J]. Journal of Phase Equilibria,1998,19(6):591.
HUANG Q,REN Y,LUO Y,et al. Deformation of MnS-MnTe inclusions in a sulfur-containing free-cutting steel with tellurium treatment[J]. Metallurgical and Materials Transactions B,2023,54:370.
[26]
SHEN P,YANG Q K,ZHANG D,et al. The effect of tellurium on the formation of MnTe-MnS composite inclusions in non-quenched and tempered steel[J]. Metals,2018,8(8):639.
[27]
SHEN P,ZHOU L,YANG Q K,et al. Modification of MnS inclusion by tellurium in 38MnVS6 micro-alloyed steel[J]. Metallurgical Research and Technology,2020,117(6):615.
[28]
KATOH T,ABEYAMA S,KIMURA A,et al. A Study on resulfurized free-machining steel containing a small amount of tellurium[J]. Denki-Seiko,1982,53(3):195.
[29]
SHEN P,ZHANG H,XU X Y,et al. Study on the high-temperature evolution and formation mechanism of inclusions in Te-treated resulfurized special steel[J]. Steel Research International,2021,92(11):2100235.
[30]
NOGI K,OGINO K. Role of interfacial phenomena in deoxidation process of molten iron[J]. Canadian Metallurgical Quarterly,1983,22(1):19.
[31]
OGINO K,NOGI K,YAMASE O. Effects of selenium and tellurium on the surface tension of molten iron and the wettability of alumina by molten iron[J]. Transactions of the Iron and Steel Institute of Japan,1983,23(3):234.
[32]
TAKADA H,BESSHO I,ITO T. Effect of sulfur content and solidification variables on morphology and distribution of sulfide in steel ingots[J]. Tetsu-to-Hagane,1976,62(10):1319.
[33]
OIKAWA K,ISHIDA K,NISHIZAWA T. Effect of titanium addition on the formation and distribution of MnS inclusions in steel during solidification [J]. ISIJ International,1997,37(4):332.
[34]
LI M L,WANG F M,LI C R,et al. Effects of cooling rate and Al on MnS formation in medium-carbon non-quenched and tempered steels[J]. International Journal of Minerals Metallurgy and Materials,2015,22(6):589.
[35]
XIA Y J,WANG F M,LI C R,et al. Study on the formation behavior of sulfides in free-cutting steel by unidirectional solidification[J]. Journal of University of Science and Technology Beijing,2012,34(2):118.
[36]
TANAKA Y,PAHLEVANI F,MOON S C,et al. In situ characterisation of MnS precipitation in high carbon steel[J]. Scientific Reports,2019,9:10096.
[37]
ZENG J,ZHU C Y,WANG W L,et al. In situ observation of the MnS precipitation behavior in high-sulfur microalloyed steel under different cooling rates[J]. Metallurgical and Materials Transactions B,2020,51(6):2522.
YAGUCHI H,ONODERA N. The effect of tellurium on the machinability of AISI12L14+Te steel[J]. Transactions of the Iron and Steel Institute of Japan,1988,28(12):1051.
XIE J B,FAN T,SUN H,et al. Enhancement of impurity,machinability and mechanical properties in Te-treated 0Cr18Ni9 steel[J]. Metals and Materials International,2021,27(6):1416.
ARKHURST B M,BAE J H,NA M Y,et al. Effect of tellurium on the microstructure and mechanical properties of Fe-14Cr oxide-dispersion-strengthened steels produced by additive manufacturing[J]. Journal of Materials Science and Technology,2021,95:114.