Abstract:The black rock series(stone coal) vanadium ore standard material development, representative of the candidate, uniformity and stability with high requirements. Through the three provinces of Hubei, Hunan, Guizhou five black rock series(stone coal) vanadium mine rock specimens of rock ore appraisal and comprehensive test of sample determination of X- ray diffraction and X- ray fluorescence spectrum and the measurement of vanadium’s valent state and phase determination of vanadium and comparative study, find out the black rock series (stone coal) vanadium ore structure and texture of commonness and characteristics, mineral components of ore deposits, as the black rock series (stone coal) vanadium ore standard material selected to provide the basis in the development of the candidate material deposit. Identifies four black rock series (stone coal) vanadium ore standard substances candidate ore deposit, and respectively from the selected multiple section collected different types of ore deposit, in accordance with the principle of preparation of a sample of a mining area, began the development of the series of standard substances.