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Numerical simulation of gas blowing effect on powder injection desulfurization during RH refining process |
SUN Liang1, SUN Yu2, CHEN Wei3, ZHANG Lifeng3 |
1. Steelmaking Department, Beijing Shougang Co., Ltd., Tangshan 064404, Hebei, China; 2. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China; 3. School of Mechanical and Materials Engineering, North China University of Technology, Beijing 100144, China |
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Abstract In order to study the influence of gas injection parameters on the powder injection desulfurization during RH refining process and improve the efficiency of desulfurization, three-dimensional coupled k-ε turbulence model, volume of fluid (VOF) model, discrete phase model (DPM), user defined scaler (UDS), and unreacted core desulfurization kinetic model were established based on the powder injection desulfurization process of an actual 230 t RH. The effects of the circulation flow rate of snorkel, injection at the vacuum chamber side, and injection at the ladle bottom on the speed and powder injection desulfurization of molten steel were discussed. The results show that the desulfurizers are mainly concentrated on the interface of vacuum chamber near the downleg side after it is sprayed into the vacuum chamber, and desulfurizers enter the ladle from the downleg with the circulating flow of molten steel. The desulfurizers in the ladle also tend to accumulate on the downleg side. The speed and desulfurization rate of molten steel increase with the increase of the circulation flow rate of snorkel, but the increase is small when the circulation flow rate (standard condition) increases from 1 000 L/min to 2 000 L/min. When the circulation flow rate continues to increase from 2 000 L/min to 3 000 L/min, the speed of molten steel increases significantly, but the end-point desulfurization efficiency only increases by 4.0%. The speed and desulfurization rate of molten steel increase slightly with the 2 000 L/min side injection at the vacuum chamber. When the gas injection with 200 L/min flow rate is carried out at the bottom of the ladle corresponding to the up snorkel, the speed of molten steel in the ladle increases significantly, but the desulfurization rate decreases due to the decrease of residence time for desulfurizer in the ladle. The study provides a theoretical basis for improving the efficiency of the powder injection desulfurization during RH refining process.
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Received: 06 June 2023
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[1] |
褚绍阳,干勇,仇圣桃,等. 高牌号无取向硅钢生产流程中织构控制研究现状[J/OL]. 材料导报:1.[2023-03-01]. http://kns.cnki.net/kcms/detail/50.1078.TB.20230630.1618.014.html.
|
[2] |
何忠治. 电工钢的现状与展望[J]. 中国冶金,2001,11(4):17.
|
[3] |
郑庆,隋亚飞,刘红军,等. 不同RH脱氧方式对含铝电工钢的影响[J]. 钢铁研究学报,2020,32(10):892.
|
[4] |
隋亚飞,李慈颖,刘彭,等. RH脱硫对无取向电工钢中夹杂物的影响[J]. 炼钢,2019,35(2):34.
|
[5] |
刘坚锋,胡金文,郭飞虎,等. 无取向电工钢RH精炼顶渣优化[J]. 炼钢,2021,37(6):28.
|
[6] |
李慈颖,隋亚飞,田飞,等. RH精炼工艺对无取向电工钢质量的影响[J]. 电工钢,2021,3(2):21.
|
[7] |
邱钰杰,虞澜,曾建华,等. RH精炼脱硫实践[J]. 钢铁研究学报,2011,23(4):19.
|
[8] |
彭玮珂,林利平. RH顶吹喷粉脱硫工艺实践[J]. 炼钢,2000,16(5):21.
|
[9] |
秦哲,廖建军,周剑峰,等. 高牌号无取向电工钢RH深脱硫[J]. 钢铁,2014,49(2):5.
|
[10] |
战东平,姜周华,罗建江,等. RH-KTB预熔渣深脱硫实践[J]. 钢铁,2005,40(11):4.
|
[11] |
赵家七,蔡小锋,邹长东. 180 t RH真空精炼炉脱硫工艺开发及应用[J]. 钢铁,2018,53(11):6.
|
[12] |
NITA P S,BUTNARIU I,CONSTANTIN N. The efficiency at industrial scale of a thermodynamic model for desulphurization of aluminium killed steels using slags in the system CaO-MgO-Al2O3-SiO[J]. Revista de Metalurgia (Madrid),2010,46(1):5.
|
[13] |
NZOTTA M M,SICHEN D,SEETHARAMAN S. Sulphide capacities in some multi component slag systems[J]. ISIJ International,2007,38(11):1170.
|
[14] |
SHANKAR A,GÖRNERUP M,SEETHARAMAN S,et al. Sulfide capacity of high alumina blast furnace slags[J]. Metallurgical and Materials Transactions B,2006,37(6):941.
|
[15] |
YANG X,SHI C,ZHANG M,et al. A thermodynamic model of sulfur distribution ratio between CaO-SiO2-MgO-FeO-MnO-Al2O3 slags and molten steel during LF refining process based on the ion and molecule coexistence theory[J]. Metallurgical and Materials Transactions B,2011,42(6):1150.
|
[16] |
WEI J,JIANG X,WEN L,et al. Mass transfer characteristics between molten steel and particles under conditions of RH-PB(IJ) refining process[J]. ISIJ International,2007,47(3):408.
|
[17] |
BROOKS G A,RHAMDHANI M A,COLEY K S. Transient kinetics of slag metal reactions[J]. Metallurgical and Materials Transactions B,2009,40(3):353.
|
[18] |
PEIXOTO J J M,GABRIEL W V,DE OLIVEIRA T A S,et al. Numerical simulation of recirculating flow and physical model of slag-metal behavior in an RH reactor:Application to desulfurization[J]. Metallurgical and Materials Transactions B,2018,49(5):2421.
|
[19] |
JEONG T S,PARK J H. Effect of fluorspar and industrial wastes (red mud and ferromanganese slag) on desulfurization efficiency of molten steel[J]. Metallurgical and Materials Transactions B,2020,51(5):2309.
|
[20] |
JEONG T S,OH M K,CHUNG Y,et al. Effect of white mud addition on desulfurization rate of molten steel[J]. Metallurgical and Materials Transactions B,2021,52(6):3596.
|
[21] |
魏季和,朱守军,郁能文. 钢液RH精炼中喷粉脱硫的动力学[J]. 金属学报,1998,34(5):497.
|
[22] |
WEI J H,ZHU S J,YU N W. Kinetic model of desulphurisation by powder injection and blowing in RH refining of molten steel[J]. Ironmaking and Steelmaking,2000,27(2):129.
|
[23] |
李素芹,熊国宏,李士琦,等. 极低硫钢的精炼脱硫动力学模型[J]. 北京科技大学学报,2004,26(3):244.
|
[24] |
胡汉涛,马志刚,蒋晓放,等. 钢液 RH 精炼中脱硫过程的数值模拟[J]. 炼钢,2013,29(5):52.
|
[25] |
ZHU C,CHEN P,GUANGQIANG L,et al. A mathematical model of desulphurization kinetics for ultra-low-sulfur steels refining by powder injection during RH processing[J]. ISIJ International,2016,56(8):1368.
|
[26] |
ZHAO Y, CHEN W, CHENG S,et al. Mathematical simulation of hot metal desulfurization during KR process coupled with an unreacted core model[J]. International Journal of Minerals,Metallurgy,and Materials,2022,29(4):758.
|
[27] |
李宝宽,栾叶君,齐凤升,等. 带有旋流的RH精炼系统循环流动的实验研究[J]. 东北大学学报,2005,26(8):759.
|
[28] |
WANG R,JIN Y,CUI H. The flow behavior of molten steel in an RH degasser under different ladle bottom stirring processes[J]. Metallurgical and Materials Transactions B,2022,53(1):342.
|
[29] |
朱苗勇,沙骏,黄宗泽. RH真空精炼装置内钢液流动行为的数值模拟[J]. 金属学报,2000,36(11):1175.
|
[30] |
GENG D,LEI H,HE J. Numerical simulation of the multiphase flow in the Rheinsahl-Heraeus (RH) system[J]. Metallurgical and Materials Transactions B,2010,41(1):234.
|
[31] |
HE S,CHEN G,GUO C. Investigation of mixing and slag layer behaviours in the RH degasser with bottom gas injection by using the VOF-DPM coupled model[J]. Ironmaking and Steelmaking,2019,46(8):771.
|
[32] |
LI Y,BAO Y,WANG R,et al. Modeling study on the flow patterns of gas-liquid flow for fast decarburization during the RH process[J]. International Journal of Minerals,Metallurgy,and Materials,2018,25(2):153.
|
[33] |
LING H,ZHANG L. Numerical simulation of gas and liquid two-phase flow in the RH process[J]. Metallurgical and Materials Transactions B,2019,50(4):2017.
|
[34] |
LING H,ZHANG L,LIU C. Effect of snorkel shape on the fluid flow during RH degassing process:mathematical modelling[J]. Ironmaking and Steelmaking,2016,45(2):145.
|
[35] |
WANG R,JIN Y,CUI H. The flow behavior of molten steel in an RH degasser under different ladle bottom stirring processes[J]. Metallurgical and Materials Transactions B,2022,53(1):342.
|
[36] |
PARK Y G,DOO W C,YI K W,et al. Numerical calculation of circulation flow rate in the degassing Rheinstahl-Heraeus process[J]. ISIJ International,2000,40(8):749.
|
[37] |
ZHANG L,LI F. Investigation on the fluid flow and mixing phenomena in a Ruhrstahl-Heraeus (RH) steel degasser using physical modeling[J]. JOM,2014,66(7):1227.
|
[38] |
ZHU B,LIU Q,KONG M,et al. Effect of interphase forces on gas-liquid multiphase flow in RH degasser[J]. Metallurgical and Materials Transactions B,2017,48(5):2620.
|
[39] |
CHEN W,ZHANG L. Effects of interphase forces on multiphase flow and bubble distribution in continuous casting strands[J]. Metallurgical and Materials Transactions B,2021,52(1):528.
|
[40] |
SANO Y,YAMAGUCHI N,ADACHI T. Mass transfer coefficients for suspended particles in agitated vessels and bubble columns[J]. Journal of Chemical Engineering of Japan,1974,7(4):255.
|
[41] |
PENG K,SUN Y,PENG X,et al. Numerical simulation on the desulfurization of the molten steel during RH vacuum refining process by CaO powder injection[J]. Metallurgical and Materials Transactions B,2023,54(1):438.
|
[42] |
OETERS F,STROHMENGER P,PLUSCHKELL W. Kinetik der entschwefelung von roheisenschmelzen mit kalk und erdgas[J]. Archiv für das Eisenhüttenwesen,1973,44(10):727.
|
|
|
|