含Cu低合金高强钢时效Cu析出研究进展

doi:10.13228/j.boyuan.issn1006-9356.20230355

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Abstract Cu-bearing low-alloy steel is a kind of important low-carbon low-alloy high-strength steel. It has excellent comprehensive application value by making up for the strength reduction of low-carbon equivalent through Cu precipitation, taking into account high strength, good welding performance, low temperature toughness and corrosion resistance. The research progress of Cu precipitation in Cu-bearing low-alloy steel at home and abroad is reviewed. Taking the hardness change curve of Cu-bearing low-alloy steel during aging treatment as an example, the change trends of mechanical properties for materials are clarified, and the strength increment formula corresponding to Cu precipitation based on precipitation strengthening mechanism is summarized. The evolution process of Cu precipitation during aging treatment is sorted out, including phase transformation, crystal structure transformation and mathematical model related to the size of Cu precipitated phase. The common added alloying elements in Cu-bearing low-alloy steel and the effect of alloying elements on Cu-bearing low-alloy are summarized. Finally, the development for new generation of Cu-bearing low-alloy steel is prospected. It is pointed out that regulating the size and distribution of Cu precipitation by optimizing the theoretical model and adding Ni-based alloying elements is an important means to prepare Cu-bearing low-alloy steel with better performance.

Key words： Cu-bearing low-alloy high-strength steel aging treatment Cu-rich phase precipitation strengthening alloy element

Received: 02 June 2023

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	Articles by authors
	LIANG Fengrui
	SU Hang
	CHAI Feng
	SUN Mingxuan

Cite this article:

LIANG Fengrui,SU Hang,CHAI Feng等. Advance in Cu precipitation during aging treatment of Cu-bearing low-alloy high-strength steel[J]. China Metallurgy, 2023, 33(11): 29-38.

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http://www.zgyj.ac.cn/EN/10.13228/j.boyuan.issn1006-9356.20230355 OR http://www.zgyj.ac.cn/EN/Y2023/V33/I11/29

[1]	XUE Q,BENSON D,MEYERS M A,et al. Constitutive response of welded HSLA 100 steel[J]. Materials Science and Engineering A,2003,354(1/2):166.
[2]	杨才福,张永权. 新一代易焊接高强度高韧性船体钢的研究[J]. 钢铁,2001,36(11):50.
[3]	朱立光,马晨雨,王旗,等. 焊接工艺对海工钢热影响区组织与性能的影响[J]. 钢铁,2023,58(2):137.
[4]	余锡模,赵世金. 含Cu和Ni低碳高强度钢等时回火析出富Cu相的研究[J]. 金属学报,2013,49(5):569.
[5]	赵吉庆,杨钢,彭涛. Cu元素对AMS6308钢抗回火性能的影响[J]. 钢铁,2021,56(4):76.
[6]	杜瑜宾,胡小锋,张守清,等. 含1.4%Cu的HSLA钢的组织和力学性能[J]. 金属学报,2020,56(10):1343.
[7]	FU W,LI C N,DI X J,et al. Improvement of Cu-rich precipitation strengthening for high-strength low carbon steel strengthened via Ti-microalloying[J]. Materials Letters,2022,316:132031.
[8]	LI C N,DUAN R,FU W,et al. Improvement of mechanical properties for low carbon ultra-high strength steel strengthened by Cu-rich multistructured precipitation via modification to bainite[J]. Materials Science and Engineering A,2021,817:141337.
[9]	胡磊,张莉芹,胡锋,等. 多尺度截面组织对调质海工钢强韧性的影响[J]. 钢铁,2023,58(2):147.
[10]	阚立烨,叶其斌,田勇,等. Cu-NiAl纳米复合析出强化钢回火工艺[J]. 钢铁,2021,56(2):105.
[11]	REN H P,WANG H Y,LIU Z C. Cu precipitation dynamics in Fe-Cu alloy[J]. Journal of Physics:Conference Series,2008,96:012206.
[12]	杜瑜宾,胡小锋,宋元元,等. 含Cu的HSLA钢中富Cu团簇的粗化行为及其对力学性能的影响[J]. 材料热处理学报,2021,42(9):136.
[13]	李振团,柴锋,杨才福,等. 淬火工艺对铜沉淀强化UHS钢组织性能的影响[J]. 钢铁,2019,54(6):79.
[14]	赵吉庆,杨钢,彭涛. Cu元素对AMS6308钢抗回火性能的影响[J]. 钢铁,2021,56(4):76.
[15]	ZHOU R Y,ZHU L H. Growth behavior and strengthening mechanism of Cu-rich particles in sanicro 25 austenitic heat-resistant steel after aging at 973 K[J]. Materials Science and Engineering A,2020,796:139973.
[16]	罗小兵,朱飞,杨才福,等. 纳米粒子强化含铜双相钢的组织性能关系[J]. 钢铁,2021,56(9):118.
[17]	李振团,柴锋,罗小兵,等. 时效温度对Cu沉淀强化超高强海工钢力学性能的影响[J]. 材料导报,2020,34(6):6132.
[18]	GUO Z L,SHA W. Quantification of precipitation hardening and evolution of precipitates[J]. Materials Transactions,2002,43(6):1273.
[19]	XIONG Z P,TIMOKHINA IP,PERELOMA E. Clustering,nano-scale precipitation and strengthening of steels[J]. Progress in Materials Science,2021,118:100764.
[20]	朱小绘,刘向兵,王润中,等. 290 ℃氩离子辐照对Fe-Cu合金微观组织的影响[J]. 金属学报,2022,58(7):905.
[21]	WANG X J,QIANG W J,SHU G G,et al. The ageing behavior and the correlation between hardness and coercivity of Cu-rich reactor pressure vessel model steels[J]. Journal of Magnetism and Magnetic Materials,2021,527:167698.
[22]	赵金龙,林鸿亮,杨春光,等. 含铜抗菌不锈钢的应用研究现状[J]. 中国冶金,2022,32(6):26.
[23]	尹鸿祥. 铁素体抗菌不锈钢的铜析出机理与性能控制[D]. 北京:北京科技大学,2016.
[24]	卫争艳,徐梅,谭国华. 时效处理对05Cr17Ni4Cu4Nb马氏体沉淀硬化不锈钢力学性能及组织的影响[J]. 特殊钢,2021,42(5):85.
[25]	RASANEN E. Decomposition of austenite in Fe-Cu alloys[J]. Scandinavian Journal of Metallurgy,1973,2(5):257.
[26]	利成宁,段然,邸新杰,等. 富Cu析出强化贝氏体超高强钢的组织特征及强韧化机制[J]. 材料热处理学报,2021,42(12):76.
[27]	SUN M X,ZHANG WN,LIU Z Y,et al. Direct observations on the crystal structure evolution of nano Cu-precipitates in an extremely low carbon steel[J]. Materials Letters,2017,187:49.
[28]	WAGNER C. Theory of precipitate change by redissolution[J]. Zeitschrift für Elektrochemie,1961,65:581.
[29]	ALEXANDROV D V. On the theory of Ostwald ripening in the presence of different mass transfer mechanisms[J]. Journal of Physics and Chemistry of Solids,2016,91:48.
[30]	ALEXANDROVA I V,IVANOV A A,ALEXANDROV D V. How the intermediate stage of a phase transition process transforms to the concluding stage of Ostwald ripening[J]. Journal of Crystal Growth,2020,532:125456.
[31]	吴志方,刘超. 二元互不溶体系中第二相颗粒的Ostwald熟化[J]. 材料导报,2016,30(5):23.
[32]	PHILIPPE T,VOORHEES P W. Ostwald ripening in multicomponent alloys[J]. Acta Materialia,2013,61(11):4237.
[33]	KAMPMANN R,WAGNER R. Kinetics of precipitation in metastable binary alloys-theory and application to Cu-1.9 at% Ti and Ni-14 at% Al[M]//Decomposition of Alloys:the Early Stages. Oxford,England:Pergamon,1984:91.
[34]	MOLNAR D,MUKHERJEE R,CHOUDHURY A,et al. Multiscale simulations on the coarsening of Cu-rich precipitates in α-Fe using kinetic Monte Carlo,molecular dynamics and phase-field simulations[J]. Acta Materialia,2012,60(20):6961.
[35]	SCHMAUDER S,BINKELE P. Atomistic computer simulation of the formation of Cu-precipitates in steels[J]. Computational Materials Science,2002,24(1):42.
[36]	郭震,赵宇宏,孙远洋,等. 相场法研究Fe-Cu-Mn-Al合金富Cu相析出机制[J]. 物理学报,2021,70(8):322.
[37]	孙铭璇,孟利,张宁,等. 低碳含Cu中厚板钢富Cu相的时效析出行为[J]. 金属热处理,2023,48(2):94.
[38]	陈晨,罗小兵,梁丰瑞,等. 淬火加热方法对含铜高强度球扁钢组织和性能的影响[J]. 热处理,2021,36(3):31.
[39]	梁梦斐,王海燕,王超,等. 合金元素Ni对Fe-Cu合金析出过程的影响[J]. 稀有金属,2021,45(1):117.
[40]	杨才福,刘翊之,柴锋,等. 高强度含铜钢奥氏体连续冷却转变产物的强韧性[J]. 北京科技大学学报,2014,36(4):438.
[41]	冷文秀,田文怀. Fe-Cu二元合金中的B2析出相及时效硬化[J]. 材料热处理学报,2009,30(3):80.
[42]	刘宗昌,李文学,王玉峰,等. Fe-1.12Cu合金中Cu的脱溶[J]. 金属热处理,2005,30(6):40.
[43]	SHEN Q,XIONG X Y,LI T,et al. Effects of co-addition of Ni and Al on precipitation evolution and mechanical properties of Fe-Cu alloy[J]. Materials Science and Engineering A,2018,723:279.
[44]	JIAO Z B,LUAN J H,MILLER MK,et al. Precipitation mechanism and mechanical properties of an ultra-high-strength steel hardened by nanoscale NiAl and Cu particles[J]. Acta Materialia,2015,97:58.
[45]	董富军,杨才福,王瑞珍. 固溶和时效工艺对10Ni3MnCuAl钢组织和硬度的影响[J]. 金属热处理,2017,42(8):110.
[46]	杨才福,张永权. Cu时效硬化钢中Cu的析出[J]. 钢铁,2005,40(4):62.
[47]	STEWART C A,FONDA R W,KNIPLING K E. Mn-stabilized austenitic steel strengthened by nano-scale β-NiAl (B2),FCC-Cu,and carbides via ICME design[J]. Scripta Materialia,2021,200:113903.
[48]	XU S S,ZHAO Y,CHEN D,et al. Nanoscale precipitation and its influence on strengthening mechanisms in an ultra-high-strength low-carbon steel[J]. International Journal of Plasticity,2019,113:99.
[49]	ZHOU B C,YANG T,ZHOU G,et al. Mechanisms for suppressing discontinuous precipitation and improving mechanical properties of NiAl-strengthened steels through nanoscale Cu partitioning[J]. Acta Materialia,2021,205:116561.
[50]	THOSTENSON E T,CHOU T W. Processing-structure-multi-functional property relationship in carbon nanotube/epoxy composites[J]. Carbon,2006,44(14):3022.
[51]	SYARIF J,TSUCHIYAMA T,TAKAKI S. Mechanism of toughening in ferritic iron by solute copper at low temperature[J]. ISIJ International,2003,43(7):1100.
[52]	杨才福,苏航,李丽,等. 高性能铜沉淀硬化船体钢[J]. 中国有色金属学报,2004(增刊1):211.
[53]	刘庆冬. HSLA铁素体钢中Cu析出强化和奥氏体韧化的原子探针层析技术研究[D]. 上海:上海大学,2012.
[54]	DU Y B,HU X F,ZHANG S Q,et al. Precipitation behavior of Cu-NiAl nanoscale particles and their effect on mechanical properties in a high-strength low-alloy steel[J]. Materials Characterization,2022,190:112014.
[55]	HAN G,XIE Z J,XIONG L,et al. Evolution of nano-size precipitation and mechanical properties in a high-strength-ductility low-alloy steel through intercritical treatment[J]. Materials Science and Engineering A,2017,705:89.
[56]	张中武,魏兴豪,赵刚. 低合金高强钢的强韧化机理与焊接性能[J]. 鞍钢技术,2018(4):1.
[57]	孙铭璇,孟利,张宁,等. 感应淬火条件下含Cu-Ni低碳低合金钢的强化机制[J]. 金属热处理,2023,48(4):204.
[58]	NAKASHIMA K,FUTAMURA Y,TSUCHIYAMA T,et al. Interaction between dislocation and copper particles in Fe-Cu alloys[J]. Transactions of the Iron and Steel Institute of Japan,2002,42(12):1541.
[59]	刘翊之,杨才福,柴锋,等. 高铜镍结构钢高温氧化层和内表层缺陷研究[J]. 材料科学与工艺,2013,21(6):78.
[60]	张中武,许松松,李俊澎,等. 一种含铜纳米相强化中锰钢及其制备方法:中国,CN106834942A[P]. 2018-08-31.