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Research status and development prospect of titanium extraction from high titanium blast furnace slag |
LIU Shuai, ZHANG Zong-wang, ZHANG Jian-liang, WANG Zhen-yang |
School of Metallurgy and Ecological Engineering, Beijing University of Science and Technology, Beijing 100083, China |
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Abstract Titanium-bearing blast furnace slag can be directly used to make raw materials such as concrete, slag wool and concrete blocks, but its valuable vanadium and titanium resources cannot be effectively utilized. China's titanium-bearing blast furnace slag reserves are large and still growing at a rapid rate every year. Therefore, the extraction of titanium resources from titanium-bearing blast furnace slag has become a research hotspot. Based on the review of the relevant research on the extraction technology of titanium from blast furnace slag, the process, advantages and disadvantages of the extraction technology of titanium from blast furnace slag from different enrichment forms such as ferrotitanium alloy, titanium dioxide and titanium tetrachloride are summarized, and the feasibility of each process is analyzed and discussed, hoping to promote the sustainable and healthy development of titanium resources and achieve the purpose of comprehensive utilization of resources.
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Received: 10 September 2019
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[1] |
王勋,韩跃新,李艳军,等. 钒钛磁铁矿综合利用研究现状[J]. 金属矿山,2019(6):33.
|
[2] |
彭毅. 攀钢高炉渣提钛技术进展[J]. 钛工业进展, 2005, 22(3): 44.
|
[3] |
张月,王海波,刘湘. 高钛高炉渣提钛综合利用研究现状[J]. 新型工业化,2018,8(8):124.
|
[4] |
郭强,袁守谦,刘军,等. 高炉渣改性作为矿渣棉原料的试验[J]. 中国冶金,2011,21(8):46.
|
[5] |
肖丽俊,刘天泉,朱果灵,等. 高炉渣改质成缓释型硅钾肥[J]. 中国冶金,2016,26(5):15.
|
[6] |
高洋,贵永亮,宋春燕,等. 高钛高炉渣综合利用现状及展望[J]. 矿产综合利用,2019(1):6.
|
[7] |
Pourabdoli M, Raygan S, Abdizadeh H, et al. A new process for the production of ferrotitanium from titania slag[J]. Canadian Metallurgical Quarterly,2007,46(1):17.
|
[8] |
豆志河,张廷安,张含博,等. 采用铝热自蔓延法制备低氧高钛铁合金[J]. 中南大学学报:自然科学版, 2012, 43(6): 2108.
|
[9] |
CHENG Chu, DOU Zhi-he, ZHANG Ting-an,et al. Distribution and control mechanism of Al and O residuals in ferrotitanium prepared by aluminothermic reduction with insufficient Al[J]. JOM, 2019, 71(2): 809.
|
[10] |
甄玉兰,张国华,周国治. 铝热法还原含钛高炉渣的试验研究[J]. 钢铁钒钛, 2014, 35(5): 40.
|
[11] |
牛丽萍,张廷安,张含博,等. 铝热还原制备高钛铁的热力学和动力学[J]. 中国有色金属学报, 2010, 20(增刊1): 425.
|
[12] |
LI Xiong, HUA Yi-xin, XU Cun-ying, et al. Effect of CaO addition on preparation of ferrotitanium from ilmenite by electrochemical reduction in CaCl2-NaCl molten salt[J]. Nonferrous Metals, 2016(676): 383.
|
[13] |
李有奇,柯昌明,侯世喜,等. 碳热法还原攀钢高钛高炉渣工艺研究[J]. 硅酸盐通报,2007(3):447.
|
[14] |
刘畅,黄润,袁溢,等. 攀枝花钛精矿真空碳热还原热力学模拟研究[J]. 钢铁钒钛, 2015, 36(4): 13.
|
[15] |
王凯飞,张国华,王璐,等. 添加Fe2O3对碳热还原含钛高炉渣的影响[J]. 过程工程学报, 2018, 18(6): 1276.
|
[16] |
GOU Hai-peng, ZHANG Guo-hua, HU Xiao-jun,et al. Kinetic study on carbothermic reduction of ilmenite with activated carbon [J]. Transactions of Nonferrous Metals Society of China, 2017, 27(8): 1856.
|
[17] |
熊瑶,李春,梁斌,等. 盐酸浸出自然冷却含钛高炉渣[J]. 中国有色金属学报, 2008, 18(3): 557.
|
[18] |
贾峰,刘荣,杨铭. 盐酸直接浸出高钛型高炉渣[J]. 南京师范大学学报:工程技术版, 2012, 12(2): 43.
|
[19] |
王曾洁,张利华,王海北,等. 盐酸常压直接浸出攀西地区钛铁矿制备人造金红石[J]. 有色金属, 2007, 59(4): 108.
|
[20] |
杨德建,刘代俊,徐程浩. 钛白废酸浸取攀钢高炉渣的研究[J]. 四川化工, 2007, 10(2): 44.
|
[21] |
仲斌年,薛天艳,胡国平,等. 磷酸活化焙烧-酸浸法富集低品位还原钛渣[J]. 过程工程学报, 2013, 13(3): 378.
|
[22] |
刘娟. 攀枝花钛资源制备沸腾氯化用富钛原料研究进展[J]. 中国有色冶金, 2018, 47(6): 49.
|
[23] |
王强,张庆武. 熔盐法处理富钛渣制备金红石型TiO2[J]. 应用化工,2008,37(2):140.
|
[24] |
薛天艳,齐涛,王丽娜,等. 钠碱熔盐法处理高钛渣制备TiO2的基础研究[C]//2008年全国冶金物理化学学术会议专辑(上册).贵阳:中国有色金属学会,中国稀土学会,中国金属学会,2008:123.
|
[25] |
李兴华,蒲江涛. 攀枝花高钛型高炉渣综合利用研究最新进展[J]. 钢铁钒钛, 2011, 32(2): 10.
|
[26] |
张荣禄. 含钛高炉渣制取四氯化钛的方法.中国:CN1033264[P].1989-06-07.
|
[27] |
彭毅. 碳化攀钢高炉渣低温选择氯化的热力学分析[J]. 钛工业进展, 2005(6): 45.
|
[28] |
Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972, 238(S8): 37.
|
[29] |
杨合,薛向欣,左良,等. 含钛高炉渣催化剂光催化降解亚甲基蓝[J]. 过程工程学报, 2004, 4(3): 265.
|
[30] |
赵娜,杨合,薛向欣,等. 高钛渣作为光催化材料降解邻硝基酚的实验研究[J]. 硅酸盐学报, 2005, 33(2): 202.
|
[31] |
仇圣桃,张明博,李建新,等. 含钛高炉渣资源化综合利用研究现状与展望[J]. 钢铁, 2016, 51(7): 1.
|
[32] |
易小祥,李亚伟,杨大兵. 攀钢含钛高炉渣碳氮化后磁选提钛研究[J]. 矿冶, 2008,17 (3): 46.
|
[33] |
隋智通,郭振中,张力,等. 含钛高炉渣中钛组分的绿色分离技术[J]. 材料与冶金学报, 2006, 5(2): 93.
|
[34] |
许仁泽,张建良,常治宇,等. 高钛型高炉渣中钛组分选择性富集与析出研究进展[J]. 钢铁钒钛, 2017, 38(6): 6.
|
[35] |
高启瑞,宋波,杨占兵,等. 含钛高炉渣碳化及超重力分离碳化钛的研究[J]. 有色金属科学与工程, 2017, 8(2): 1.
|
|
|
|