Abstract:The specification and quality of rack steel used for offshore drilling platforms have an important impact on the scope and life of offshore platforms. In order to inhibit the oxidative burn loss of B element in steel in the process of electroslag remelting (ESR), and ensure the prograde of the remelting process and low cost, the basic slag with qualified melting temperature was designed by combining the melting point of rack steel and the CaF2-CaO-Al2O3 phase diagram. The effects of MgO and B2O3 on the melting point, viscosity, and electrical conductivity of basic slag were studied using FactSage 8.2 software and relevant empirical formulas. The relationship between the content of MgO and B2O3 and the dissolved oxygen and the equilibrium B element content was analyzed by the mass action concentrations based on the coexistence theory of slag structure. The suitable electroslag remelting slag for remelting B-containing rack steel was obtained, and the viscosity of the slag was determined by high temperature test. The results show that the melting point range of suitable slag for remelting rack steel is 1 309-1 409 ℃, and MgO can reduce the electrical conductivity of slag and improve the viscosity, but MgO has almost no effect on the oxygen potential and activity of B2O3. With the increase of B2O3 content in the slag, both the turning point temperature and the precipitation amount of the high melting point phase decreases. The slag used for remelting B-containing rack steel with the best performance is 57.08%CaF2-20.83%CaO-22.09%Al2O3-4%MgO-5%B2O3.
PATEISKY G, BIELE H, FLEISCHER H J. The reactions of titanium and silicon with Al2O3-CaO-CaF2 slags in the ESR process[J]. Journal of Vacuum Science and Technology, 1972, 9(6): 1318.
[10]
MEDINA S, CORES A. Thermodynamic aspects in the manufacturing of microalloyed steels by the electroslag remelting process[J]. ISIJ International, 1993, 33(12): 1244.
[11]
REYES-CARMONA F, MITCHELL A. Deoxidation of ESR slags[J]. ISIJ International, 1992, 32(4): 529.
[12]
MITCHELL A. The chemistry of ESR slags[J]. Canadian Metallurgical Quarterly, 1981, 20(1): 101.
[13]
JIANG Z H, HOU D, DONG Y W, et al. Effect of slag on titanium, silicon, and aluminum contents in superalloy during electroslag remelting[J]. Metallurgical and Materials Transactions B, 2016, 47: 1465.
[14]
LI S, CHENG G, HUANG Y, et al. Mathematical model for design of optimized multi-component slag for electroslag remelting[J]. Journal of Iron and Steel Research International, 2020, 27: 380.
[15]
陈恩普. 铁基、镍基、钴基合金熔点计算方法和经验公式[J]. 特殊钢, 1992(2):28.
[16]
李正邦. 电渣冶金的理论与实践[M]. 北京: 冶金工业出版社, 2010.
[17]
姜周华, 董艳伍, 耿鑫, 等. 电渣冶金学[M]. 北京: 科学出版社, 2015.
[18]
PENG L, JIANG Z, GENG X. Design of ESR slag for remelting 9CrMoCoB steel under simple protective Ar gas[J]. Metals, 2019, 9(12): 1300.
[19]
OGINO K, HASHIMOTO H, HARA S. Measurement of the electrical conductivity of ESR fluxes containing fluoride by four electrodes method with alternating current[J]. Tetsu-to-Hagane, 1978, 64(2): 225.
LI T, LI G, LIU Y, et al. Effect of MgO on the fluoride vaporization and crystallization of CaF2-CaO-Al2O3-(MgO) slag for vacuum electroslag remelting[J]. Journal of Thermal Analysis and Calorimetry, 2022, 147: 11445.
[24]
LI W, CAO X, JIANG T, et al. Relation between electrical conductivity and viscosity of CaO-SiO2-Al2O3-MgO system[J]. ISIJ International, 2016, 56(2): 205.
MILLS K C, SRIDHAR S. Viscosities of ironmaking and steelmaking slags[J]. Ironmaking and Steelmaking, 1999, 26(4): 262.
[28]
HAWKINS R, SWINDEN D, POCKLINGTON D. Electroslag Refining[M]. London:The Iron and Steel Institute,1973.
[29]
TAYLOR C R. Equilibria of liquid iron and simple basic slags in a rotating induction furnace[J]. Trans. AIME, 1943, 154: 228.
[30]
FRASER ME, MITCHELL A. Mass transfer in the electroslag process. Part1: mass-transfer model[J]. Ironmaking and Steelmaking, 1976(3), 279.
[31]
MITCHELL A, SZEKELY J, ELLIOTT J. Electroslag Refining[M]. London:The Iron and Steel Institute, 1973.
[32]
YANG X, SHI C, ZHANG M, et al. A thermodynamic model for prediction of iron oxide activity in some FeO-Containing slag systems[J]. Steel Research International, 2012, 83(3): 244.
HOU D, JIANG Z, DONG Y, et al. Thermodynamic design of electroslag remelting slag for high titanium and low aluminum stainless steel based on IMCT[J]. Ironmaking and Steelmaking, 2016, 43(7): 517.
LI S, CHENG G, YANG L, et al. A thermodynamic model to design the equilibrium slag compositions during electroslag remelting process: description and verification[J]. ISIJ International, 2017, 57(4): 713.
DONG Y W, JIANG Z H, CAO Y L, et al. Effect of slag on inclusions during electroslag remelting process of die steel[J]. Metallurgical and Materials Transactions B, 2014, 45: 1315.