Situation and research development on resource utilization of metallurgical dust containing zinc in iron and steel industry
LI Qiang1,2,3, CHEN Tiejun1,4, LI Qiyong2,3, ZHOU Xianlin1,4, SHI Yanhong2, CHEN Wangyuan2
1. School of Resources and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081, Hubei, China; 2. Resources and Chemical Engineering of San Ming University, Sanming 365004, Fujian, China; 3. Fujian Provincial Key Laboratory of Resources and Environment Monitoring and Sustainable Management and Utilization, Sanming 365004, Fujian, China; 4. Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan 430081, Hubei, China
Abstract:Metallurgical dust containing zinc is bulk solid waste in iron and steel industry, but it also contains a variety of valuable components. The main methods of treating metallurgical dust containing zinc in iron and steel industry are analyzed, namely, in-plant circulation treatment process, rotary kiln treatment process and rotary hearth furnace treatment process, the in-plant circulation treatment process combined with the rotary hearth furnace treatment process is more in line with the current environmental protection policy requirements. The resource utilization methods of metallurgical dust containing zinc are analyzed, the hydrometallurgical leaching method, vacuum metallurgy method, chloridizing volatilization method, selective reduction method and other methods are difficult to achieve environment-friendly and efficient industrial application, while microwave reduction method can effectively overcome the existing problems of rotary hearth furnace treatment process, and has good research significance and application prospect.
李强, 陈铁军, 李奇勇, 周仙霖, 施艳鸿, 陈王媛. 钢铁行业含锌冶金尘泥资源化利用现状与研究进展[J]. 中国冶金, 2023, 33(7): 1-9.
LI Qiang, CHEN Tiejun, LI Qiyong, ZHOU Xianlin, SHI Yanhong, CHEN Wangyuan. Situation and research development on resource utilization of metallurgical dust containing zinc in iron and steel industry[J]. China Metallurgy, 2023, 33(7): 1-9.
BOGDAN E O,PAVLYUKEVICH Y G,LARIONOV P S,et al. Comprehensive analysis of the physicochemical properties of metallurgical dust for determining the main directions of its reprocessing[J]. Glass and Ceramics,2020,77(5/6):183.
NIU F S,HE S T,ZHANG J X,et al. Study on ultrasonically-enhanced deep eutectic solvents leaching of zinc from zinc-containing metallurgical dust sludge[J]. Metals,2022,12(11):1856.
LI Y,FENG H X,WANG J S,et al. Current status of the technology for utilizing difficult-to-treat dust and sludge produced from the steel industry[J]. Journal of Cleaner Production,2022,367:132909.
LI N,WANG F. Numerical analysis of radiative heat transfer and direct reduction of three-dimensional multilayer ellipsoidal carbon-containing pellet unit in the rotary hearth furnace[J]. Metals,2020,10(8):994.
WU Y L,JIANG Z Y,ZHANG X X,et al. Process optimization of metallurgical dust recycling by direct reduction in rotary hearth furnace[J]. Powder Technology,2018,326:101.
[22]
LI K J,ZHANG J L,LIU Z J,et al. Comprehensive evaluation of OxyCup process for steelmaking dust treatment based on calculation of mass balance and heat balance[J]. Journal of Iron and Steel Research International,2014,21(6):575.
VERES J,JAKABSKY S,LOVAS M. Comparison of conventional and microwave assisted leaching of zinc from the basic oxygen furnace dust[J]. Mineralia Slovaca,2010,42(3):369.
SANTOS F,BROCCHI E,ARAUJO V,et al. Behavior of Zn and Fe content in electric arc furnace dust as submitted to chlorination methods[J]. Metallurgical and Materials Transactions B,2015,46(4):1729.
[41]
王谦,GRAYDON J W,KIRK D W. FeCl2处理电炉炉尘的热力学计算[J]. 重庆大学学报(自然科学版),2003,26(6):73.